Journal
RUSSIAN CHEMICAL BULLETIN
Volume 61, Issue 9, Pages 1726-1732Publisher
SPRINGER
DOI: 10.1007/s11172-012-0238-8
Keywords
organolanthanides; yttrium; lanthanum; ytterbium; lutetium; diphenylcyclopentadiene; triphenylcyclopentadiene; tetraphenylcyclopentadiene; phenylcyclopentadienyl complexes
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Funding
- Russian Foundation for Fundamental Research [11-03-00043, 10-03-00953]
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Reaction of LnCl(3)(thf) (x) (Ln = Y, La, Yb, Lu) with NaCpPhn (Cp-Phn = 1,3-Ph2C5H3, 1,2,4-Ph3C5H2, Ph4C5H) leads to formation of monocyclopentadienyl dichloride complexes Yb(Ph2C5H3)Cl-2(thf)(3) (1), Ln(Ph3C5H2)Cl-2(thf)(3) (Ln = Y (2), Lu (3)), La(Ph4C5H)Cl-2(thf)(3) (4). Molecular structures of 1, 2 and the polynuclear complex [(Ph3C5H2)(3)Lu-4(Cl)(7)(O)(thf)(3)] (5), which is a partial hydrolysis product of 3, have been established by the X-ray method.
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