Journal
RUSSIAN CHEMICAL BULLETIN
Volume 58, Issue 1, Pages 101-107Publisher
SPRINGER
DOI: 10.1007/s11172-009-0015-5
Keywords
self-assembly; thiacalix[4]arenes; molecular recognition; dynamic light scattering (DLS); silver cations; photoswitchers
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Funding
- Russian Foundation for Basic Research [06-03-32160, 08-03-90403-Ukr, 08-03-91106-AFGIR]
- CRDF [RUC1-2910-KA-07]
- Ministry of Science and Education of the Russian Federation [REC-007, BP2M07]
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New p-tert-butyl thiacalix[4]arene tetrasubstituted at the lower rim and containing the azobenzene fragments in the 1,3-alternate configuration was synthesized. Its receptor proper-ties with respect to d-metal cations (Fe3+, Cu2+, Ag+) were studied using UV spectroscopy and dynamic light scattering (DLS). The ability of p-tert-butyl thiacalix[4]arene to molecular recognition of silver cations was estimated by UV spectroscopy. The aggregation of these systems was studied by the dynamic light scattering method.
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