Journal
RUSSIAN CHEMICAL BULLETIN
Volume 58, Issue 5, Pages 944-947Publisher
SPRINGER
DOI: 10.1007/s11172-009-0120-5
Keywords
5-silaspiro[4.4]non-2-ene; anionic polymerization; dimerization; cyclic oligomers; organosilicon compounds
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Synthesis of 5-silaspiro[4.4]non-2-ene and its low-temperature anionic polymerization with the ring opening have been accomplished. A dimer and cyclic oligomers with higher degree of polymerization are predominantly formed under the action of (BuLi)-Li-n in THF at -78 A degrees C.
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