Journal
RUSSIAN CHEMICAL BULLETIN
Volume 57, Issue 1, Pages 83-89Publisher
SPRINGER
DOI: 10.1007/s11172-008-0012-0
Keywords
limonene; liquid-phase oxidation; hydroperoxides; kinetic parameters; kinetic model
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The kinetic regularities of the autooxidation of R(+)-limonene (LH) were experimentally studied at various temperatures. A kinetic model including the main elementary reactions and the corresponding rate constants was developed. The degenerate chain branching during limonene oxidation proceeds via bimolecular reactions and involves hydroperoxide LOOH + LH -> L-center dot + LO center dot + H2O and LOOH + LOOH -> LO center dot + LO2 center dot + H2O.
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