Journal
RHEOLOGICA ACTA
Volume 53, Issue 8, Pages 593-605Publisher
SPRINGER
DOI: 10.1007/s00397-014-0776-0
Keywords
Capillary bridging; Percolation; Pendular network; Ternary blends
Categories
Funding
- National Science Foundation (NSF-CBET) [0932901]
- Div Of Chem, Bioeng, Env, & Transp Sys
- Directorate For Engineering [1336311, 0932901] Funding Source: National Science Foundation
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We investigate the structure and rheology of a melt-blended ternary system composed of a continuous polymer phase, silica particles in the few-micron size range, and a small amount of a second immiscible polymer phase which preferentially wets the particles. The morphology of the ternary system is found to consist of a volume-spanning pendular network of particles bridged by menisci of the wetting polymer, as well as capillary aggregates which are large compact particle aggregates saturated by the wetting polymer. The ternary blends have strongly non-Newtonian melt rheology due to the pendular network. The relative extent of capillary aggregation depends on the melt-blending history, and the rheological properties can be used to track the changes in the blend structure. The pendular network is seen at a particle loading of only 10 vol.%, demonstrating that capillary bridging lowers the percolation threshold of a particle-filled polymer.
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