Journal
RESEARCH ON CHEMICAL INTERMEDIATES
Volume 41, Issue 6, Pages 3759-3765Publisher
SPRINGER
DOI: 10.1007/s11164-013-1487-3
Keywords
Condensation; beta-Enaminones; Pyridine; Cerium chloride; Michael addition; Cyclodehydration
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Funding
- MLP Network
- CSIR
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One-pot condensation of aryl/heteroaryl beta-enaminones and ammonium acetate in the presence of CeCl3 center dot 7H(2)O-NaI led to the formation of novel (aryl/heteroaryl)(6-(aryl/heteroaryl)pyridin-3-yl)methanone in very good yields. Mechanistically, the reaction proceeds via tandem, regioselective Michael addition-cyclodehydration-elimination sequence.
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