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Efficient one-pot synthesis of 1-carbamatoalkyl-2-naphthols using aluminum methanesulfonate as a reusable catalyst

Journal

RESEARCH ON CHEMICAL INTERMEDIATES
Volume 39, Issue 5, Pages 2123-2131

Publisher

SPRINGER
DOI: 10.1007/s11164-012-0744-1

Keywords

Carbamatoalkyl naphthol; Aluminum methanesulfonate; Multicomponent reaction; Solvent-free

Funding

  1. Education Committee of Liaoning Province of China [L2011198]

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A wide range of 1-carbamatoalkyl-2-naphthols were synthesized via a one-pot three-component condensation of 2-naphthol, aldehydes, and carbamates in the presence of aluminum methanesulfonate at 70 A degrees C under solvent-free conditions. The catalyst is reusable and could be recycled for several runs without any distinct decrease in its efficiency. A plausible mechanism for this three-component reaction was proposed.

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