Journal
REACTIVE & FUNCTIONAL POLYMERS
Volume 71, Issue 6, Pages 625-633Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.reactfunctpolym.2011.03.001
Keywords
Methacrylate monomers; Suspension polymerization; Microspheres; Porous polymers; Textural properties; Thermal analysis; Chromatographic retention selectivity of polymers
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Permanently porous copolymers derived from multifunctional methacrylate monomers were prepared by suspension polymerization. The polymerization process was carried out in the presence of toluene and decan-1-ol used as pore forming diluents. Influence of chemical structure of monomers on porous structure of the studied microspheres, the residual C=C bonds, and their thermal properties was studied. Moreover, chromatographic retention selectivity of methacrylate microspheres was determined and compared with the commercially available polymeric stationary phase - Porapak Q. (C) 2011 Elsevier Ltd. All rights reserved.
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