4.7 Article

A hydrophilic matrix for boron isolation: Monodisperse-porous poly(glycidyl methacrylate-co-ethylene dimethacrylate) particles carrying diol functionality

Journal

REACTIVE & FUNCTIONAL POLYMERS
Volume 70, Issue 8, Pages 555-562

Publisher

ELSEVIER
DOI: 10.1016/j.reactfunctpolym.2010.05.004

Keywords

Boron; Boron-selective sorbents; Modified seeded polymerization; Monodisperse-porous particles; Adsorption

Funding

  1. BOREN [2008-G-0192]
  2. TUBITAK

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The novel chelating adsorbent has been synthesized by functionalization of monodisperse-porous poly(glycidyl methacrylate-co-ethylene dimethacrylate) particles with N-methylglucamine (NMDG) as a boron selective ligand. The resulting resin can adsorb boron in almost all pH range (pH 4-10) and its maximum capacity is ca. 12 mg/g. The adsorption behavior of poly(GMA-co-EDM)NMDG resin obeyed Langmuir isotherm well. (C) 2010 Elsevier Ltd. All rights reserved.

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