4.1 Article

FLAVONOIDS, NORISOPRENOIDS AND OTHER TERPENES FROM LEAVES OF Tapirira guianensis

Journal

QUIMICA NOVA
Volume 31, Issue 8, Pages 2056-2059

Publisher

SOC BRASILEIRA QUIMICA
DOI: 10.1590/S0100-40422008000800027

Keywords

Tapirira guianensis; norisoprenoides; fatty acid esters of triterpenes

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From hexane fraction of methanol extract of leaves of Tapirira guianensis (Anacardiaceae) were obtained lupeol, 24-methylenecycloartan-3-ol, phytol, alpha-amyrin, beta-amyrin, sitosterol, sitostenone, glycosyl sitosterol, as well as sitosterol esterified with palmitic and stearic acids. Phytol, alpha- amyrin and beta- amyrin esterified with fatty acids were also identified from same extract. The EtOAc extract besides the norisoprenoids (6S,7E,9S)-6,9-dihydroxy-megastigma-4,7-dien-3-one 9-O-beta-glucopyranoside and (6S,7E,9R)-6,9-dihydroxy-megastigma-4,7-dien-3-one 9-O-beta-glucopyranoside also afforded kaempferol 3-O-rhamnoside, kaempferol 3-O-arabinofuranoside, quercetin 3-O-rhamnoside, and kaempferol. The structural elucidation of isolated compounds were based on UV, IR, MS, (1)H and (13)C NMR data analysis.

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