Journal
CATALYSIS SCIENCE & TECHNOLOGY
Volume 5, Issue 9, Pages 4636-4643Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cy00891c
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Funding
- Region Wallonne in the frame of the CO2Green project
- Region Wallonne in the frame of the Sinopliss project
- Region Wallonne in the frame of the Flycoat project
- Belgian Science Policy in the frame of the Interuniversity Attraction Poles Programme - Functional Supramolecular Systems [IAP VII/5]
- Fonds National pour la Recherche Scientifique (F.R.S.-FNRS)
- IDEX (Initiative d'Excellence) program of the University of Bordeaux
- University of Liege
- FRIA (Fond pour la Recherche dans l'Industrie et l'Agriculture)
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A catalytic platform based on an onium salt used in combination with organic cocatalysts of various structures was developed for the efficient CO2/epoxide coupling under mild conditions. Through detailed kinetic studies by in situ FT-IR spectroscopy, a rational investigation of the efficiency of a series of commercially available hydrogen bond donors co-catalysts was realized and the influence of different parameters such as the pressure, the temperature, the catalyst loading, and the nature of the epoxide on the reaction kinetics was evaluated. Fluorinated alcohols were found to be more efficient than other hydrogen bond donor activators proposed previously in the literature under similar conditions.
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