Journal
PURE AND APPLIED CHEMISTRY
Volume 83, Issue 11, Pages 2041-2053Publisher
WALTER DE GRUYTER GMBH
DOI: 10.1351/PAC-CON-11-03-04
Keywords
beta-cyclodextrins; electrocatalysis; gold nanoparticles; modified electrodes; silicate sol-gel matrix; sensors
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Funding
- Department of Science and Technology (DST), New Delhi
- CSIR-SRF
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Metal nanoparticles encapsulated by silicate sol-gel matrix find numerous applications particularly in electrocatalysis and sensors. In our previous reports, we have reported the mono- and bi-metal gold, silver, and core/shell gold/silver nanoparticles embedded in functionalized silicate sol-gel matrices. Modified electrodes were fabricated using mono-and bi-metallic gold, silver, and core/shell gold/silver nanoparticles embedded in silicate sol-gel, and they were used for the electrocatalysis and sensing of H2O2 and simultaneous detection of hydrazine, sulfite, and nitrite. We have prepared the gold nanoparticles encapsulated by amine-functionalized silicate sol-gel matrix in a single step without using any external reducing agents. The gold nanoparticles were also synthesized by using amine-functionalized silane monomer in the presence of beta-cyclodextrin (beta-CD), resulting in metal/polymer core/shell nanostructures. This nanocomposite material showed a synergistic stabilizing effect when compared to either silicate sol-gel matrix or beta-CD alone as stabilizer. The synthesized gold nanoparticles were characterized using UV-vis spectroscopy and high-resolution transmission electron microscopy. Modified electrodes were prepared by using the gold nanoparticles embedded in silicate sol-gel matrix, and their electrochemical characteristics were studied.
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