Journal
PURE AND APPLIED CHEMISTRY
Volume 82, Issue 4, Pages 953-968Publisher
INT UNION PURE APPLIED CHEMISTRY
DOI: 10.1351/PAC-CON-09-09-17
Keywords
acenes; alkynes; heterocycles; organic chemistry; organic electronics
Categories
Funding
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [0848833] Funding Source: National Science Foundation
Ask authors/readers for more resources
The history and development of pyrazine- and pyridine-type heteroacenes and their use in solid-state organic electronics are discussed and reviewed. The larger N-heteroacenes are potential electron- or hole-transporting materials and should therefore complement acenes in organic electronics. As they feature electronegative nitrogen ring atoms in their molecular skeleton, issues with oxidation should be less problematic when comparing them to the larger acenes such as pentacene. This paper covers the synthesis and the solid-state packing of larger (tetracene/pentacene-based) N,N-heterocylic acenes as well as the question of the interplay of aromaticity and antiaromaticity in the known larger N-heteroacenes and their N,N-dihydro-derivatives; also illuminated are their optical properties. A literature overview is provided.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available