Journal
PURE AND APPLIED CHEMISTRY
Volume 82, Issue 4, Pages 1001-1009Publisher
WALTER DE GRUYTER GMBH
DOI: 10.1351/PAC-CON-09-09-09
Keywords
alkynes; charge transfer; click chemistry; conjugated polymers; cycloaddition; electrochemistry; thermal properties
Categories
Funding
- Grants-in-Aid for Scientific Research [22685023] Funding Source: KAKEN
Ask authors/readers for more resources
A high-yielding addition reaction between electron-rich alkynes and a small acceptor molecule, tetracyanoethylene (TCNE), was employed as a new click reaction to construct donor-acceptor chromophores in the polymer main chains and side chains. The donor-acceptor alternating conjugated polymers were prepared from the ferrocene-containing poly(aryleneethynylene)s in one step and atom-economic fashion. The energy levels and thermal properties of the aromatic polyamines substituted by electron-rich alkynes as a side chain can be tunable by the amount of the added TCNE. The resulting donor-acceptor-type polymers feature broad charge-transfer (CT) bands in the visible region, potent redox activities, and improved thermal properties.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available