Journal
PURE AND APPLIED CHEMISTRY
Volume 82, Issue 11, Pages 2005-2016Publisher
WALTER DE GRUYTER GMBH
DOI: 10.1351/PAC-CON-09-12-06
Keywords
aerobic oxidation; gold nanoclusters; heterocyclization; hydroamination; Lewis acid
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Gold nanoclusters (NCs) stabilized by the poly(N-vinyl-2-pyrrolidone) hydrophilic polymer (Au:PVP) behave not only as aerobic oxidation catalyst but also formal Lewis acid catalyst, which promotes the intramolecular heterocyclization of gamma-hydroxyalkenes and gamma-aminoalkenes.
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