Journal
PURE AND APPLIED CHEMISTRY
Volume 80, Issue 5, Pages 993-1003Publisher
WALTER DE GRUYTER GMBH
DOI: 10.1351/pac200880050993
Keywords
organosulfur; transition metals; catalysis; addition; C-H substitution; metathesis
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Rhodium complexes are efficient catalysts for the synthesis of organosulfur compounds. They catalyze the addition reaction of organosulfur groups to unsaturated compounds, the substitution of C-H with organosulfur groups, and single-bond metathesis reactions. They cleave S-S bonds and transfer the organosulfur groups to various organic and inorganic molecules, including alkynes, allenes, disulfides, sulfur, isonitriles, imines, diphosphines, thiophosphinites, hydrogen, 1-alkylthio-1-alkynes, thioesters, and allyl sulfides.
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