Journal
PURE AND APPLIED CHEMISTRY
Volume 80, Issue 5, Pages 861-871Publisher
WALTER DE GRUYTER GMBH
DOI: 10.1351/pac200880050861
Keywords
ruthenium catalysis; allylic substitution; regioselectivity
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Recent developments in the chemistry of eta(3)-allylruthenium(IV) complexes are due to their straightforward synthesis resulting from oxidative addition of allylic substrates to a ruthenium(II) center. Subsequent reaction with a nucleophile is the basis of their involvement in the catalytic allylic substitution reaction. We focus here on ruthenium-catalyzed substitution of allylic substrates by C-, N-, and O-nucleophiles and show that selected ligands make regio- and enantioselective reactions possible.
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