Journal
PURE AND APPLIED CHEMISTRY
Volume 80, Issue 4, Pages 707-715Publisher
WALTER DE GRUYTER GMBH
DOI: 10.1351/pac200880040707
Keywords
palladium-catalyzed coupling; aryl bromides; aryl triflates; thiol surrogates; benzothiazole; xantphos
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The carbon-sulfur bond formation of aryl bromides and triflates catalyzed by a new catalyst system, Pd-2(dba)(3)/xantphos, has been demonstrated. Based on this finding, a novel and practical synthesis of benzothiazoles has been developed. This new methodology allows for the assembly of a wide range of benzothiazoles.
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