Journal
PURE AND APPLIED CHEMISTRY
Volume 80, Issue 4, Pages 695-706Publisher
WALTER DE GRUYTER GMBH
DOI: 10.1351/pac200880040695
Keywords
heterocycles; ring-opening cyclization; alkylidenecyclopropanes; cyclopropenes; catalysis
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Alkylidenecyclopropyl, cyclopropenyl, or azacyclocyclopropenyl ketones or carboxylates have been demonstrated to be versatile starting materials for the synthesis of oxygen- and/or nitrogen-containing heterocycles. The reactivitics, and regioselectivities may be nicely controlled by subtle choice of the catalysts and reaction condition parameters.
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