Journal
PURE AND APPLIED CHEMISTRY
Volume 80, Issue 5, Pages 929-939Publisher
WALTER DE GRUYTER GMBH
DOI: 10.1351/pac200880050929
Keywords
nickel; alkenes; allenes; alkynes; aldehydes; isocyanates
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Funding
- NIGMS NIH HHS [R01 GM063755-09, R01 GM072566, R25 GM063775, R01 GM063755] Funding Source: Medline
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Several reactions of simple, unactivated alkenes with electrophiles under Ni(0) catalysis are discussed. The coupling of olefins with aldehydes and silyl triflates provides allylic or homoallylic alcohol derivatives, depending on the supporting ligands and, to a lesser extent, the substrates employed. Reaction of alkenes with isocyanates yields N-alkyl acrylamides. In these methods, alkenes act as the functional equivalents of alkenyl- and allylmetal reagents.
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