Journal
ADVANCED ENERGY MATERIALS
Volume 5, Issue 8, Pages -Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/aenm.201402041
Keywords
-
Categories
Funding
- NSF [CBET-1435912]
- Office of Naval Research (ONR) [N00014-11-1-0317]
- Div Of Chem, Bioeng, Env, & Transp Sys
- Directorate For Engineering [1435912] Funding Source: National Science Foundation
Ask authors/readers for more resources
Unlike universally applicable fullerene derivatives, current nonfullerene electron acceptors are rarely effective with more than one donor polymer in bulk heterojunction (BHJ) solar cells. A novel class of nonfullerene electron acceptors, bis(naphthalene imide)-3,6-diphenyl-trans-anthrazolines (BNIDPAs), that is applicable and yields efficient photovoltaic devices with multiple donor polymers, including a thiazolothiazole-dithienosilole copolymer (PSEHTT) and benzodithiophene copolymers (PBDTT-FTTE and PTB7) is reported. Photovoltaic devices composed of the BNIDPA-butyloctyl (BO) acceptor with PSEHTT, PBDTT-FTTE, and PTB7, respectively, have power conversion efficiencies of 3.0%-3.1% with high open-circuit voltages of approximate to 1.0 V. In contrast, BHJ devices composed of BNIDPA-DT acceptor with larger 2-decyltetradecyl chains and the same donor polymers have substantially reduced bulk electron mobility and reduced photovoltaic efficiencies of 1.3%-1.7%, which highlight the critical role of the size of alkyl chains appended onto nonfullerene electron acceptors. The present results provide a rare example of nonfullerene electron acceptors that are capable of pairing with multiple donor polymers to achieve efficient BHJ solar cells.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available