Journal
ACS CATALYSIS
Volume 5, Issue 11, Pages 6713-6718Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acscatal.5b01604
Keywords
metal-organic framework; ethylene dimerization; gas-phase reaction; (bipyridyl)nickel complexes; catalysis
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Funding
- Camille and Henry Dreyfus Postdoctoral Program in Environmental Chemistry
- DTRA [HDTRA1-14-1-0014]
- Energy Frontier Research Center - U.S. Department of Energy (DOE), Office of Science, Basic Energy Sciences (BES) [DE-SC0012702]
- U.S. Department of Energy, Office of Basic Energy Sciences, Division of Chemical Sciences, Geosciences, and Biosciences [DE-AC02-06CH11357]
- International Institute for Nanotechnolog, NSF-MRSEC [DMR-1121262]
- Keck Foundation
- state of Illinois
- Northwestern University
- Inorganometallic Catalyst Design Center
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NU-1000-(bpy)Ni-II, a highly porous MOF material possessing well-defined (bpy)Ni-II moieties, was prepared through solvent-assisted ligand incorporation (SALI). Treatment with Et2AlCl affords a single-site catalyst with excellent catalytic activity for ethylene dimerization (intrinsic activity for butenes that is up to an order of magnitude higher than the corresponding (bpy)NiCl2 homogeneous analogue) and stability (can be reused at least three times). The high porosity of this catalyst results in outstanding levels of activity at ambient temperature in gas-phase ethylene dimerization reactions, both under batch and continuous flow conditions.
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