Journal
ACS CATALYSIS
Volume 5, Issue 5, Pages 2770-2773Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acscatal.5b00258
Keywords
ruthenium; alkylation; oxa- and azabicyclic alkenes; oxygen; C-H bond activation
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Funding
- China Scholarship Council (CSC)
- Alexander von Humboldt Foundation
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A ruthenium-catalyzed arylation reaction of oxa- and azabicyclic alkenes with (hetero)arenes by C-H bond activation has been discovered. The reaction does not require additives and utilizes dioxygen in realizing the catalytic cycle leading to monosubstituted 7-oxa and 7-azabenzonor-bornane derivatives.
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