Journal
ACS CATALYSIS
Volume 5, Issue 2, Pages 853-858Publisher
AMER CHEMICAL SOC
DOI: 10.1021/cs501860b
Keywords
cobalt catalysis; C-H amidation; acetoxycarbamates; 6-arylpurines; arylamines
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Funding
- Institute for Basic Science in Korea [IBS-R10-D1]
- Ministry of Science, ICT & Future Planning, Republic of Korea [IBS-R010-D1-2015-A00] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
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The Co(III)-catalyzed direct C-H amidation of arenes has been developed using O-acylcarbamates as a convenient amino source. This reaction proceeded in high efficiency under external oxidant-free conditions with a broad range of arene substrates, including 6-arylpurines bearing sensitive functional groups, thus furnishing synthetically versatile arene N-carbamate products.
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