Journal
ACS CATALYSIS
Volume 6, Issue 1, Pages 230-234Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acscatal.5b02218
Keywords
ruthenium catalysis; C-H bond activation; alkenylation; hydrogen evolution; oxidant free; ambient temperature
Categories
Funding
- INSA, India [SP/YSP/99/2014]
- CSIR
Ask authors/readers for more resources
A ruthenium-catalyzed oxidant-free highly regioselective ortho alkenylation of substituted aromatics such as aromatic amides, aromatic ketoximes, and anilides with alkenes in the presence of AgSbF6 and acetic acid in ClCH2CH2Cl at room temperature is described. The alkenylation reaction provides ortho alkenylated aromatics along with evolution of H-2 gas. In the reaction, no oxidant was used, and the whole catalytic reaction has occurred without changing the oxidation state of the metal.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available