Journal
PROPELLANTS EXPLOSIVES PYROTECHNICS
Volume 37, Issue 5, Pages 527-535Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/prep.201100151
Keywords
DNBTDO; Nitrogen heterocycles
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Funding
- Ludwig-Maximilian University of Munich (LMU)
- Fonds der Chemischen Industrie (FCI)
- European Research Office (ERO) of the U.S. Army Research Laboratory (ARL)
- Armament Research, Development and Engineering Center (ARDEC) [W911NF-09-2-0018, W911NF-09-1-0120, W011NF-09-1-0056]
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Energetic tetrazine-1,3-dioxide, 5,7-dinitrobenzo-1,2,3,4-tetrazine-1,3-dioxide (DNBTDO), was synthesized in 45?% yield. DNBTDO was characterized as an energetic material in terms of performance (Vdet 8411 m?s-1; pC?J 3.3 x 1010 Pa at a density of 1.868 g?cm-3), mechanical sensitivity (impact and friction as a function of grain size), and thermal stability (Tdec 204 degrees C). DNBTDO exhibits a sensitivity slightly higher than that of RDX, and a performance slightly lower (96?% of RDX).
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