Journal
ACS CATALYSIS
Volume 5, Issue 11, Pages 6328-6336Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acscatal.5b01656
Keywords
core-shell nanoparticles; ORR; durability; AuNi alloy; Pt shell; density functional theory (DFT)
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Funding
- US Department of Energy, Division of Chemical Sciences [DE-SC0012704]
- Office of Science of the U.S. DOE [DE-AC02-05CH11231]
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Improving the activity and stability of Pt-based core-shell nanocatalysts for proton exchange membrane fuel cells while lowering Pt loading has been one of the big challenges in electrocatalysis. Here, using density functional theory, we report the effect of adding Au as the third element to enhance the durability and activity of Ni@Pt core-shell nanoparticles (NPs) during the oxygen reduction reaction (ORR). Our results show that the durability and activity of a Ni@Pt NP can be finely tuned by controlling Au concentration and distribution. For a NiAu@Pt NP, the durability can be greatly promoted by thermodynamically favorable segregation of Au to replace the Pt atoms at vertex, edge, and (100) facets on the shell, while still keeping the ORR activity on the active Pt(111) shell as high as that of Ni@Pt nanoparticles. Such behavior strongly depends on a direct interaction with the Ni interlayer. Our results not only highlight the importance of interplay between surface strain on the shell and the interlayer-shell interaction in determining the durability and activity but also provide guidance on how to maximize the usage of Au to optimize the performance of core-shell (Pt) nanoparticles. Such understanding has allowed us to discover a novel NiAu@Pt nanocatalyst for the ORR.
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