Journal
ACS CATALYSIS
Volume 5, Issue 11, Pages 6458-6462Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acscatal.5b01753
Keywords
cobalt; C-C bond activation; base metal; beta-carbon elimination; alcohols
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Funding
- Max-Planck-Society/Max-Planck-Institut fur Kohlenforschung
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We demonstrate that a simple Co(III)-complex can efficiently catalyze the cleavage of unstrained C-C bonds via the beta-carbon elimination of secondary and tertiary alcohols bearing a directing group. The cobalt-aryl intermediate generated under the reaction conditions can be trapped by different electrophiles to generate a new carbon carbon bond. Some essential features of this new Co-based mechanistic manifold were revealed by preliminary mechanistic studies.
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