Journal
PROGRESS IN SURFACE SCIENCE
Volume 89, Issue 1, Pages 56-79Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.progsurf.2013.11.001
Keywords
Metal organic framework; Gas adsorption; Adsorption sites
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Funding
- European Commission
- TUBA-GEBIP Programme
- KUTEM (Koc University TUPRAS Energy Center)
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Metal organic frameworks (MOFs) are a new class of nanoporous materials that have many potential advantages over traditional nanoporous materials for several chemical technologies including gas adsorption, catalysis, membrane-based gas separation, sensing, and biomedical devices. Knowledge on the interaction of guest molecules with the MOF surface is required to design and develop these MOF-based processes. In this review, we examine the importance of identification of gas adsorption sites in MOFs using the current state-of-the-art in experiments and computational modeling. This review provides guidelines to design new MOFs with useful surface properties that exhibit desired performances, such as high gas storage capacity, and high gas selectivity. (C) 2013 Elsevier Ltd. All rights reserved.
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