Journal
PROGRESS IN POLYMER SCIENCE
Volume 38, Issue 1, Pages 63-235Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.progpolymsci.2012.06.002
Keywords
Controlled/living radical polymerization; Nitroxide-mediated polymerization; Nitroxide; Alkoxyamine; Macromolecular architecture; Polymerization process; Kinetics; Polymerization in dispersed media
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Funding
- French Ministry of Research
- CNRS
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Nitroxide-mediated polymerization (NMP) is a controlled/living radical polymerization (CLRP) technique that enables the design of well-defined, functional and complex macromolecular architectures. This comprehensive review covers all aspects, features and achievements of NMP, from its discovery to 2012. All topics related to NMP are thoroughly discussed and detailed in-depth: synthetic approaches to nitroxides and alkoxyamines, kinetic aspects and polymerization features, range of controllable monomers, polymer characterization, polymerization processes (ionic liquids, dispersed media, etc.), macromolecular coupling approaches, functionalization strategies, macromolecular architectures, bio-related and hybrid materials, industrial applications as well as environmental constraints. (C) 2012 Elsevier Ltd. All rights reserved.
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