Journal
PROGRESS IN PHOTOVOLTAICS
Volume 23, Issue 6, Pages 765-772Publisher
WILEY
DOI: 10.1002/pip.2494
Keywords
CIGS; selenization; chalcopyrite; solar cells; photovoltaics
Funding
- Foundational Program to Advance Cell Efficiency (F-PACE) - Department of Energy of the USA [DE-EE0005407]
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The control of composition and bandgap in chalcopyrite thin-film absorber layers formed by a metal precursor reaction is addressed. Two processes using reaction with either H2Se or H2S as the final step of a three-step reaction process were compared as follows: a three-step H2Se/Ar/H2S reaction and a three-step H2Se/Ar/H2Se reaction. In both processes, significant Ga homogenization was obtained during the second-step Ar anneal, but the third-step selenization resulted in Ga depletion near the Cu(InGa)Se-2 surface, whereas the third-step sulfization did not. Solar cells were fabricated using absorbers formed using each method, and the surface Ga depletion significantly affected device performances. The solar cell incorporating the sulfization yielded a better device performance, with an efficiency of 14.4% (without an anti-reflection layer) and an open-circuit voltage of 609mV. The bandgap control in the metal precursor reaction is discussed in conjunction with the device behavior. Copyright (c) 2014 John Wiley & Sons, Ltd.
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