Journal
PROGRESS IN ORGANIC COATINGS
Volume 76, Issue 4, Pages 654-661Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.porgcoat.2012.12.005
Keywords
Tung oil; Diels-Alder; Nonisocyanate polyurethane; Acrylates
Funding
- Doctoral Research Fund of GuangZhou Medical University
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UV-curable tung oil based resins of GMA-PCDMAT and GMA-ICDMAT were synthesized via Diels-Alder reaction with maleic anhydride (MA), subsequent nonisocyanate polyurethane (NIPU) reaction with piperazine-1,4-dicarboxylic acid bis-(2-hydroxy-ethyl) ester (PCD) or isophoronediamine-1,4-dicarboxylic acid bis-(2-hydroxy-ethyl) ester (ICD) and acrylated modification with glycidyl methacrylate (GMA). The final chemical structures of GMA-PCDMAT and GMA-ICDMAT depend on the feeding ratio of MA, tung oil, PCD (or ICD) and GMA. Results of H-1 NMR and FTIR revealed that the targeted tung oil-based resins were successfully obtained. All the obtained resins had broad molecular weight distributions. UV-curing kinetic and thermal properties were respectively revealed by photo-DSC, DSC and TG. Higher concentration of C=C bonds led to faster curing rate but lower final conversion of C=C bonds. All the cured films had two glass transitions, one in the range of 8-10 degrees C and another in the range of 46-48 degrees C. All the cured films possessed excellent thermal stability, and the start temperature of decomposition (T-sta) was as high as 350 degrees C, implying that they can be used for UV coatings for the substrates with high-temperature resistance. The introduction of structure of NIPU is helpful to enhance adhesion of the cured films with substrates. (c) 2013 Elsevier B.V. All rights reserved.
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