Journal
PROGRESS IN ORGANIC COATINGS
Volume 75, Issue 4, Pages 398-403Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.porgcoat.2012.07.007
Keywords
Photopolymerization; Volume shrinkage; Hybrid monomer; Combination initiator; Chain transfer agent; Adhesion strength
Funding
- National Natural Science Foundation of China [51073014]
- Fundamental Research Funds for the Central Universities [ZZ1214]
- Program for Changjiang Scholars and Innovative Research Team in University [50473024]
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This article explored one method to decrease the volume shrinkage for photopolymerization including synthesis of a series of methacrylate-vinyl ether hybrid monomer, combination initiator system and introduction of chain transfer agent. Its photopolymerization kinetics was monitored by Fourier transform real-time infrared spectroscopy (FTIR) and the volume shrinkage is measured by using laser displacement sensor (LDS), the adhesion strength is also evaluated. The results indicated that the volume shrinkage could be adjusted in some degree on demand which is good for adhesion strength. (C) 2012 Elsevier B.V. All rights reserved.
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