Journal
PROGRESS IN ORGANIC COATINGS
Volume 70, Issue 1, Pages 16-22Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.porgcoat.2010.09.012
Keywords
ATR-FTIR; Spectro-electrochemistry; Interface; Conversion coating; Zinc
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This work investigates the hidden interface between a conversion-coated zinc surface and a polymer coating upon exposure to an electrolyte by simultaneous in situ ATR-FTIR and EIS. Various system properties were distinguished, such as the ingress of electrolyte constituents, and an active process of water-induced alterations of the conversion layer. The interface between a polymer film and a surface treated metal surface is of considerable fundamental and technical interest in many areas of application, and the results obtained open up the use of this method for a wide range of important applications. (C) 2010 Elsevier B.V. All rights reserved.
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