4.7 Article

Simple Arrhenius-type function accurately predicts dissolved oxygen saturation concentrations in aquatic systems

Journal

PROCESS SAFETY AND ENVIRONMENTAL PROTECTION
Volume 88, Issue 5, Pages 335-340

Publisher

ELSEVIER
DOI: 10.1016/j.psep.2010.05.002

Keywords

Dissolved oxygen; Chloride concentration; Aqueous solubility; Aquatic system

Funding

  1. Australian Department of Education, Science and Training
  2. Office of Research & Development at Curtin University of Technology, Perth, Western Australia
  3. State Government of Western Australia through Western Australian Energy Research Alliance (WA:ERA)

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A sufficient supply of dissolved oxygen (DO) is vital for life in higher organisms. In aquatic systems, oxygen regulates respiratory metabolism, mediates biogeochemical cycles, and is an integral component of water quality. In this work, a simple predictive tool for dissolved oxygen saturation concentrations in aquatic systems as a function of chloride concentration and temperature using a novel Arrhenius-type asymptotic exponential function has been formulated. The proposed method predicts the amount of dissolved oxygen saturation concentrations for temperatures up to 50 C and chloride concentrations up to 25 g/l. Estimations are found to be in excellent agreement with the reliable data in the literature with average absolute deviation being 3%. The tool developed in this study can be of immense practical value for the engineers and scientists to have a quick check on the oxygen saturation concentrations in aquatic systems at various conditions without opting for any experimental measurements. In particular, environmental science experts would find the proposed approach to be user-friendly with transparent calculations involving no complex expressions. (C) 2010 The Institution of Chemical Engineers. Published by Elsevier B.V. All rights reserved.

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