Journal
NATURE COMMUNICATIONS
Volume 6, Issue -, Pages -Publisher
NATURE PUBLISHING GROUP
DOI: 10.1038/ncomms7668
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Funding
- NorthEastern Center for Chemical Energy Storage, an Energy Frontier Research Center - U.S. Department of Energy, Office of Science [DE-SC0001294]
- DOE-EERE under the Batteries for Advanced Transportation Technologies (BATT) Program [DE-AC02-98CH10886, DE-SC0012704]
- World Premier Materials grant - Korea government Ministry of Trade, Industry and Energy
- 'Center on Nanostructuring for Efficient Energy Conversion' (CNEEC), an Energy Frontier Research Center - US Department of Energy, Office of Science [DE-SC0001060]
- Nuclear Research and Development Program of National Research Foundation (NRF) - Ministry of Science, ICT and Future Planning (MSIP), Republic of Korea
- US Department of Energy, Office of Basic Energy Sciences [DE-AC02-98CH10886, DE-SC0012704]
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Transition metal fluorides are an appealing alternative to conventional intercalation compounds for use as cathodes in next-generation lithium batteries due to their extremely high capacity (3-4 times greater than the current state-of-the-art). However, issues related to reversibility, energy efficiency and kinetics prevent their practical application. Here we report on the synthesis, structural and electrochemical properties of ternary metal fluorides ((MyM1-yFx)-M-1-F-2: M-1, M-2 = Fe, Cu), which may overcome these issues. By substituting Cu into the Fe lattice, forming the solid-solution CuyFe1-yF2, reversible Cu and Fe redox reactions are achieved with surprisingly small hysteresis (<150 mV). This finding indicates that cation substitution may provide a new avenue for tailoring key electrochemical properties of conversion electrodes. Although the reversible capacity of Cu conversion fades rapidly, likely due to Cu+ dissolution, the low hysteresis and high energy suggest that a Cu-based fluoride cathode remains an intriguing candidate for rechargeable lithium batteries.
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