4.8 Article

Stereospecific cis- and trans-ring fusions arising from common intermediates

Publisher

NATL ACAD SCIENCES
DOI: 10.1073/pnas.1407613111

Keywords

Diels-Alder cycloaddition; cyclobutenone; angular methylation; mechanistic studies

Funding

  1. National Institutes of Health [HL25848]
  2. Weill Cornell Medical College for a National Cancer Institute postdoctoral fellowship [CA062948]
  3. National Science Foundation

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Highly concise and stereospecific routes to cis and trans fusion, carrying various functionality at one of the bridgehead carbons, have been accomplished.

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