Journal
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA
Volume 109, Issue 29, Pages 11558-11563Publisher
NATL ACAD SCIENCES
DOI: 10.1073/pnas.1203743109
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Funding
- Marie-Heim-Voegtlin Grant [PMPDP2_134151/1]
- Swiss National Science Foundation [200021-121577/1]
- Swiss National Science Foundation-National Center of Competence in Research program Molecular Ultrafast Science and Technology
- European Research Council under the European Community [257096]
- Swiss National Science Foundation (SNF) [PMPDP2_134151] Funding Source: Swiss National Science Foundation (SNF)
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The photochemical reactivity of osmocene in a biphasic water-organic solvent system has been investigated to probe its water splitting properties. The photoreduction of aqueous protons to hydrogen under anaerobic conditions induced by osmocene dissolved in 1,2-dichloroethane and the subsequent water splitting by the osmocenium metal-metal dimer formed during H-2 production were studied by electrochemical methods, UV-visible spectrometry, gas chromatography, and nuclear magnetic resonance spectroscopy. Density functional theory computations were used to validate the reaction pathways.
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