Journal
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA
Volume 107, Issue 15, Pages 6687-6692Publisher
NATL ACAD SCIENCES
DOI: 10.1073/pnas.0912121107
Keywords
hydration; equilibrium constant; water clusters
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Funding
- National Science Foundation
- Cooperative Institute for Research in Environmental Sciences
- NASA
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [1011770] Funding Source: National Science Foundation
- Div Atmospheric & Geospace Sciences
- Directorate For Geosciences [0749145] Funding Source: National Science Foundation
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In aqueous solution, aldehydes, and to a lesser extent ketones, hydrate to form geminal diols. We investigate the hydration of methylglyoxal (MG) in the gas phase, a process not previously considered to occur in water-restricted environments. In this study, we spectroscopically identified methylglyoxal diol (MGD) and obtained the gas-phase partial pressures of MG and MGD. These results, in conjunction with the relative humidity, were used to obtain the equilibrium constant, K-P, for the water-mediated hydration of MG in the gas phase. The Gibbs free energy for this process, Delta G degrees, obtained as a result, suggests a larger than expected gas-phase diol concentration. This may have significant implications for understanding the role of organics in atmospheric chemistry.
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