4.8 Article

Finite-temperature critical point of a glass transition

Publisher

NATL ACAD SCIENCES
DOI: 10.1073/pnas.1006306107

Keywords

critical behavior; supercooled liquids

Funding

  1. US National Science Foundation
  2. US Department of Energy [DE-AC02-05CH11231]
  3. US Office of Naval Research [N00014-07-10689]

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We generalize the simplest kinetically constrained model of a glass-forming liquid by softening kinetic constraints, allowing them to be violated with a small rate. We demonstrate that this model supports a first-order dynamical (space-time) phase transition between active (fluid) and inactive (glass) phases. The first-order phase boundary in this softened model ends in a finite-temperature dynamical critical point, which may be present in natural systems. In this case, the glass phase has a very large but finite relaxation time. We discuss links between the dynamical critical point and quantum phase transitions, showing that dynamical phase transitions in d dimensions map to quantum transitions in the same dimension, and hence to classical thermodynamic phase transitions in d + 1 dimensions.

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