4.8 Article

A little bit of lithium does a lot for hydrogen

Publisher

NATL ACAD SCIENCES
DOI: 10.1073/pnas.0908262106

Keywords

high pressure; hydrogen metallization; lithium chemistry

Funding

  1. National Science Foundation (NSF) [CHE-0613306, DMR-0601461, DMR-0907425]
  2. NSF
  3. National Center for Supercomputing Applications
  4. Division Of Materials Research
  5. Direct For Mathematical & Physical Scien [907425] Funding Source: National Science Foundation

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From detailed assessments of electronic structure, we find that a combination of significantly quantal elements, six of seven atoms being hydrogen, becomes a stable metal at a pressure approximately 1/4 of that required to metalize pure hydrogen itself. The system, LiH6 (and other LiHn), may well have extensions beyond the constituent lithium. These hypothetical materials demonstrate that nontraditional stoichiometries can considerably expand the view of chemical combination under moderate pressure.

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