Journal
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA
Volume 106, Issue 36, Pages 15154-15159Publisher
NATL ACAD SCIENCES
DOI: 10.1073/pnas.0901571106
Keywords
Grotthuss mechanism; 2D infrared spectroscopy
Categories
Funding
- U. S. Department of Energy [DE-FG02-99ER14988, DE-FG02-05ER46260]
- American Chemical Society Petroleum Research Fund
- Carlsberg Foundation
- Camille and Henry Dreyfus Foundation
- U.S. Department of Energy (DOE) [DE-FG02-05ER46260] Funding Source: U.S. Department of Energy (DOE)
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It is generally accepted that the anomalous diffusion of the aqueous hydroxide ion results from its ability to accept a proton from a neighboring water molecule; yet, many questions exist concerning the mechanism for this process. What is the solvation structure of the hydroxide ion? In what way do water hydrogen bond dynamics influence the transfer of a proton to the ion? We present the results of femtosecond pump-probe and 2D infrared experiments that probe the O-H stretching vibration of a solution of dilute HOD dissolved in NaOD/D2O. Upon the addition of NaOD, measured pump-probe transients and 2D IR spectra show a new feature that decays with a 110-fs time scale. The calculation of 2D IR spectra from an empirical valence bond molecular dynamics simulation of a single NaOH molecule in a bath of H2O indicates that this fast feature is due to an overtone transition of Zundel-like H3O2- states, wherein a proton is significantly shared between a water molecule and the hydroxide ion. Given the frequency of vibration of shared protons, the observations indicate the shared proton state persists for 2-3 vibrational periods before the proton localizes on a hydroxide. Calculations based on the EVB-MD model argue that the collective electric field in the proton transfer direction is the appropriate coordinate to describe the creation and relaxation of these Zundel-like transition states.
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