4.7 Article

On the electrical conductivity and photocatalytic activity of aluminum-doped zinc oxide

Journal

POWDER TECHNOLOGY
Volume 253, Issue -, Pages 360-367

Publisher

ELSEVIER SCIENCE BV
DOI: 10.1016/j.powtec.2013.12.001

Keywords

Aluminum-doped zinc oxide; Electrical conductivity; Photocatalytic activity; Post-calcining; Photodegradation

Funding

  1. National Natural Science Foundation of China (NSFC) [21246002, 20876100]
  2. National Basic Research Program of China (973 Program) [2009CB219904]
  3. National Post-doctoral Science Foundation [20090451176]
  4. Key Lab. of Environmental Materials and Environmental Engineering of Yangzhou University [K11025]
  5. Technology Innovation Foundation of MOST [11C26223204581]
  6. Natural Science Foundation of Jiangsu Prov. [BK2011328]
  7. 333 Talent project of Jiangsu Prov.
  8. Project Academic Program Development of Jiangsu Higher Education Institutions (PAPD)
  9. Minjiang Scholarship of Fujian Prov.

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Aluminum-doped zinc oxide (AZO) conductive powders have been successfully prepared by a simple chemical coprecipitation method. The obtained powders with different post-calcining atmospheres were characterized using X-ray powder diffraction (XRD), scanning electron microscopy (SEM/EDS), and dynamic light scattering (DLS). The resistivity-dependent photocatalytic activity was studied by degradation of methyl orange (MO) in aqueous solution. The result showed that photodegradation of methyl orange dyes obeyed the rule of a pseudo first-order kinetics reaction and the AZO photocatalytic activity was related to the resistivity under different post-calcining atmospheres. (C) 2013 Elsevier B.V. All rights reserved.

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