Journal
POWDER METALLURGY AND METAL CERAMICS
Volume 49, Issue 11-12, Pages 702-706Publisher
SPRINGER
DOI: 10.1007/s11106-011-9291-3
Keywords
ceramics; silicon carbide; titanium boride; boron carbide; anodic oxidation; titanium oxides; polarization curves; Auger spectroscopy
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Polarization curves and Auger spectroscopy are used to study the kinetics, formation mechanism, and layer-by-layer phase composition of oxide films resulting from the anodic oxidation of SiC-TiB2-B4C ceramics containing 10 wt.% and 40 wt.% TiB2 in 3% NaCl solution. It is shown that a two-layer oxide film forms in the former case (beta-Ti2O3 is the lower layer and TiO2 the upper one) and a three-layer film forms in the latter case (nonstoichiometric beta-TiO is the upper and lower layers and beta-Ti2O3 the intermediate one). All ceramic samples, especially those with 10 wt.% TiB2, have high corrosion resistance.
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