Journal
POLYMERS FOR ADVANCED TECHNOLOGIES
Volume 22, Issue 12, Pages 2382-2391Publisher
WILEY-BLACKWELL
DOI: 10.1002/pat.1774
Keywords
poly(butylene terephthalate) (PBT); flammability; metal oxide; nanocomposite; aluminum diethylphosphinate
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The pyrolysis and the flame retardancy of poly(butylene terephthalate) (PBT) containing aluminum diethylphosphinate (AlPi) and nanometric Fe2O3 were investigated using thermal analysis, evolved gas analysis (Thermogravimetry-FTIR), flammability tests (LOI, UL 94), cone calorimeter measurements and chemical analysis of residue (FTIR). AlPi mainly acts as a flame inhibitor in the gas phase, through the release of diethylphosphinic acid. A small amount of Fe2O3 in PBT promotes the formation of a carbonaceous char in the condensed phase. The combination of 5 and 8 wt% AlPi, respectively, with 2 wt% metal oxides achieves V-0 classification in the UL 94 test thanks to complementary action mechanisms. Using PBT/metal oxide nanocomposites shows a significant increase in the flame retardancy efficiency of AlPi in PBT and thus opens the route to surprisingly sufficient additive contents as low as 7 wt%. Copyright (C) 2010 John Wiley & Sons, Ltd.
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