Journal
POLYMER SCIENCE SERIES B
Volume 56, Issue 2, Pages 109-117Publisher
MAIK NAUKA/INTERPERIODICA/SPRINGER
DOI: 10.1134/S1560090414020031
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- Russian Foundation for Basic Research [11-03-00640]
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The pseudoliving radical binary copolymerization of acrylonitrile with methyl acrylate, styrene, n-butyl acrylate, and tert-butyl acrylate in bulk in the presence of the reversible addition-fragmentation chain-transfer agent dibenzyl trithiocarbonate is performed for the first time. The addition of trithiocarbonate makes it possible to prepare a narrowly dispersed visually optically transparent copolymer in a wide range of monomer-feed compositions even at limiting conversions. Conditions for the synthesis of acrylonitrile copolymers with controlled molecular masses and narrow molecular-mass distributions are ascertained. In the above copolymers, the trithiocarbonate group is shown to be located within the chain.
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