Journal
POLYMER JOURNAL
Volume 47, Issue 2, Pages 195-200Publisher
SPRINGERNATURE
DOI: 10.1038/pj.2014.88
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Funding
- MEXT [2206, 23107528, 25107730, 23656544, 20685011, 70406833]
- Supported Program for the Strategic Research Foundation at Private Universities
- Grants-in-Aid for Scientific Research [25107730, 20685011, 26810103, 23656544] Funding Source: KAKEN
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Polymeric chain-structured complexes were prepared with helical lanthanide complexes (LnL; Ln = Eu-III, Tb-III, Gd-III) and benzene-dicarboxylate derivatives (benzene-1,4-dicarboxylate (bdc), 2-aminoterephtalate (atpa) and 2-hydoloxyterephtalate (htpa)), which show some noteworthy physicochemical properties, photoluminescence and thermal stabilities. The complex EuL-bdc shows bright luminescence originating from Eu-III by UV excitation. The emission color can be tuned by mixing with TbL. The structures of these chain complexes were clarified with synchrotron X-ray powder diffraction measurements. The derivation of the linker moiety (bdc, atpa or htpa) was found to affect the intermetal energy transfer from Tb-III to Eu-III.
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