4.4 Article

Chitin-chitosan nanocomposite gels: reinforcement of chitosan hydrogels with rod-like chitin nanowhiskers

Journal

POLYMER JOURNAL
Volume 44, Issue 7, Pages 713-717

Publisher

NATURE PUBLISHING GROUP
DOI: 10.1038/pj.2012.11

Keywords

chitin nanowhiskers; chitosan; degree of swelling; hydrogels; mechanical properties; nanocomposite gels

Funding

  1. Ministry of Education, Culture, Sports, Science, and Technology [22750202]
  2. Ministry of Education and Science, Japan
  3. Grants-in-Aid for Scientific Research [22750202] Funding Source: KAKEN

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Nanocomposite gels containing chitosan as a network polymer and chitin nanowhiskers as reinforcing fillers were prepared by cross-linking with the blocked isocyanate hexamethylene-1,6-di-(aminocarboxysulfonate) (HDS). Young's modulus and stress at break of the nanocomposite gels increased to maximum values of 169 and 135 kPa, respectively, with increase in whisker content up to 13.3%, whereas the degree of swelling decreased from 357 to 33.0. Polymer Journal (2012) 44, 713-717; doi: 10.1038/pj.2012.11; published online 14 March 2012

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