Journal
POLYMER INTERNATIONAL
Volume 63, Issue 7, Pages 1288-1294Publisher
WILEY
DOI: 10.1002/pi.4672
Keywords
multi-nozzle; bubble electrospinning; nanofiber yarn; mechanical properties
Categories
Funding
- National Natural Science Foundation of China [51203196]
- United Foundation from the National Natural Science Foundation of China
- People's Government of Henan Province for Cultivating Talents [U1204510]
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A novel multi-nozzle bubble electrospinning apparatus, including spinning unit, metering pump, constant flow pump, metal funnel and yarn winder, was designed for the preparation of continuous twisted polyacrylonitrile nanofiber yarns, and the principle of nanofiber yarn spinning was studied. An innovative spinning unit consisting of nozzle and air chamber was used to improve the production of nanofibers. Double conjugate electrospinning was developed using two pairs of oppositely charged spinning units to neutralize the charges. The effects of applied voltage, air flow rate, overall solution flow rate and funnel rotary speed on the fiber diameter, production rate and mechanical properties of the nanofiber yarns were analyzed. Nanofibers could be aggregated stably and bundled continuously, then twisted into nanofiber yarns uniformly at an applied voltage of 34 kV, air flow rate of 1200 mL min(-1) and overall solution flow rate of 32 mL h(-1). With an increase in the funnel rotary speed, the twist angle of the nanofiber yarns gradually increased when the take-up speed was constant. The yarn tensile strength and elongation at break showed an increasing trend with increasing twist angle. Nanofiber yarns obtained using this novel method could be produced at a rate from 2.189 to 3.227 g h(-1) with yarn diameters ranging from 200 to 386 mu m. Nanofiber yarns with a twist angle of 49.7 degrees showed a tensile strength of 0.592 cN dtex(-1) and an elongation at break of 65.7%. (C) 2013 Society of Chemical Industry
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