Journal
POLYMER INTERNATIONAL
Volume 62, Issue 3, Pages 345-352Publisher
WILEY
DOI: 10.1002/pi.4407
Keywords
porous polymers; nanoporous; carbon dioxide capture; sequestration; CCS
Categories
Funding
- Engineering and Physical Sciences Research Council
- E.ON through the E.ON-EPSRC strategic call on CCS [EP/G061785/1]
- Royal Society
- People Programme (Marie Curie Actions) of the European Union [PIEF-GA-2011-300534]
- EPSRC [EP/G061785/1] Funding Source: UKRI
- Engineering and Physical Sciences Research Council [EP/G061785/1] Funding Source: researchfish
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We review the design and use of microporous polymers for pre- and post-combustion capture of CO2. Microporous organic polymers are promising candidates for CO2 capture materials. They have good physicochemical stabilities and high surface areas. Ultrahigh-surface-area microporous organic polymers could find use in pre-combustion capture, while networks with lower surface areas but higher heats of sorption for CO2 might be more relevant for lower pressure, post-combustion capture. We discuss strategies for enhancing CO2 uptakes including increasing surface area, chemical functionalization to provide high-enthalpy binding sites and the potential for pore size tuning. (c) 2013 Society of Chemical Industry
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